EVANGELISTA TORICELLI (1608- 47)

1640 – Italy

‘Together with VINCENZO VIVIANI (1622-1703) realised that the weight of air pushing on a reservoir of mercury can force the liquid to rise into a tube that contains no air; that is, a vacuüm’

In 1650 OTTO VON GUERICKE (1602-1686) invented an air pump and showed that if you remove the air from the centre of two hemispheres that are resting together, the pressure of the outside air is sufficient to prevent a team of horses from pulling them apart.

1657 – Formed the Accademia del Cimento with eight other Florentines to build their own apparatus and conduct experiments to advance the pursuit of knowledge. Disbanded after ten years as a condition of its patron Leopoldo de Medici’s appointment as cardinal, its dissolution followed Galileo’s trial by the Catholic Church and marked the decline of free scientific research in Italy.

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BLAISE PASCAL (1623- 62)

1647 – France

Portrait of BLAISE PASCAL

BLAISE PASCAL

‘When pressure is applied anywhere to an enclosed fluid, it is transmitted uniformly in all directions’

EVANGELISTA TORICELLI (1608-47) had argued that air pressure falls at higher altitudes.

Using a mercury barometer, Pascal proved this on the summit of the 1200m high Puy de Dome in 1647. His studies in this area led to the development of PASCAL’S PRINCIPLE, the law that has practical applications in devices such as the car jack and hydraulic brakes. This is because the small force created by moving a lever such as the jacking handle in a sizable sweep equates to a large amount of pressure sufficient to move the jack head a few centimetres.
The unit of pressure is now termed the pascal.

‘The study of the likelihood of an event’

Together with PIERRE DE FERMAT, Pascal developed the theory of probabilities (1654) using the now famous PASCAL’S TRIANGLE.

Chance is something that happens in an unpredictable way. Probability is the mathematical concept that deals with the chances of an event happening.

Probability theory can help you understand everything from your chances of winning a lottery to your chances of being struck by lightning. You can find the probability of an event by simply dividing the number of ways the event can happen by the total number of possible outcomes.
The probability of drawing an ace from a full pack of cards is 4/52 or 0.077.

Probability ranges from 1 (100%) – Absolutely certain, through Very Likely 0.9 (90%) and Quite Likely 0.7 (70%), Evens (Equally Likely) 0.5 (50%), Not Likely 0.3 (30%) and Not Very Likely 0.2 (20%), to Never – Probability 0 (0%).

Picture of the 'Pascaline'. The French mathematician Blaise Pascal invented the a mechanical calculation machine. He called it the Pascaline. The Pascaline was made out of clock gears and levers and could solve basic mathematical problems like addition and subtraction.

 
 

The computer language Pascal is named in recognition of his invention in 1644 of a mechanical calculating machine that could add and subtract.

 
 
 

Like many of his contemporaries, Pascal did not separate philosophy from science; in his book ‘Pensees’ he applies his mathematical probability theory to the problem of the existence of God. In the absence of evidence for or against God’s existence, says Pascal, the wise man will choose to believe, since if he is correct he will gain his reward, and if he is incorrect he stands to lose nothing.

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ROBERT BOYLE (1627- 91)

1662 – England

‘The volume of a given mass of a gas at constant temperature is inversely proportional to its pressure’

If you double the pressure of a gas, you halve its volume. In equation form: pV = constant; or p1V1 = p2V2 where the subscripts 1 & 2 refer to the values of pressure and volume at any two readings during the experiment.

Born at Lismore Castle, Ireland, Boyle was a son of the first Earl of Cork. After four years at Eton College, Boyle took up studies in Geneva in 1638. In 1654 he moved to Oxford where in 1656, with the philosopher John Locke and the architect Christopher Wren, he formed the experimental Philosophy Club and met ROBERT HOOKE, who became his assistant and with whom he began making the discoveries for which he became famous.

Robert Boyle. New Experiments Physico-Mechanical. Oxford: Thomas Robinson, 1662

New Experiments Physico-Mechanical 1662

In 1659, with Hooke, Boyle made an efficient vacuum pump, which he used to experiment on respiration and combustion, and showed that air is necessary for life as well as for burning. They placed a burning candle in a jar and then pumped the air out. The candle died. Glowing coal ceased to give off light, but would start glowing again if air was let in while the coal was still hot. In addition they placed a bell in the jar and again removed the air. Now they could not hear it ringing and so they found that sound cannot travel through a vacuum.

Boyle proved Galileo’s proposal that all matter falls at equal speed in a vacuum.

He established a direct relationship between air pressure and volumes of gas. By using mercury to trap some air in the short end of a ‘J’ shaped test tube, Boyle was able to observe the effect of increased pressure on its volume by adding more mercury. He found that by doubling the mass of mercury (in effect doubling the pressure), the volume of the air in the end halved; if he tripled it, the volume of air reduced to a third. His law concluded that as long as the mass and temperature of the gas is constant, then the pressure and volume are inversely proportional.

Boyle appealed for chemistry to free itself from its subservience to either medicine or alchemy and is responsible for the establishment of chemistry as a distinct scientific subject. His work promoted an area of thought which influenced the later breakthroughs of ANTOINE LAVOISIER (1743-93) and JOSEPH PRIESTLY (1733-1804) in the development of theories related to chemical elements.

Boyle extended the existing natural philosophy to include chemistry – until this time chemistry had no recognised theories.

The idea that events are component parts of regular and predictable processes precludes the action of magic.
Boyle sought to refute ARISTOTLE and to confirm his atomistic or ‘corpuscular’ theories by experimentation.

In 1661 he published his most famous work, ‘The Skeptical Chymist’, in which he rejected Aristotle’s four elements – earth, water, fire and air – and proposed that an element is a material substance consisting at root of ‘primitive and simple, or perfectly unmingled bodies’, that it can be identified only by experiment and can combine with other elements to form an infinite number of compounds.

The book takes the form of a dialogue between four characters. Boyle represents himself in the form of Carneades, a person who does not fit into any of the existing camps, as he disagrees with alchemists and sees chemists as lazy hobbyists. Another character, Themistius, argues for Aristotle’s four elements; while Philoponus takes the place of the alchemist, Eleutherius stands in as an interested bystander.

In the conclusion he attacks chemists.

page from one of Boyle's publications“I think I may presume that what I have hitherto Discursed will induce you to think, that Chymists have been much more happy finding Experiments than the Causes of them; or in assigning the Principles by which they may be best explain’d”
He pushes the point further: “me thinks the Chymists, in the searches after truth, are not unlike the Navigators of Solomon’s Tarshish Fleet, who brought home Gold and Silver and Ivory, but Apeas and Peacocks too; For so the Writings of several (for I say not, all) of your Hermetick Philosophers present us, together with divers Substantial and noble Experiments, Theories, which either like Peacock’s feathers made a great show, but are neither solid nor useful, or else like Apes, if they have some appearance of being rational, are blemished with some absurdity or other, that when they are Attentively consider’d, makes them appear Ridiculous”

The critical message from the book was that matter consisted of atoms and clusters of atoms. These atoms moved about, and every phenomenon was the result of the collisions of the particles.

He was a founder member of The Royal Society in 1663. Unlike the Accademia del Cimento the Royal Society thrived.

Like FRANCIS BACON he experimented relentlessly, accepting nothing to be true unless he had firm empirical grounds from which to draw his conclusions. He created flame tests in the detection of metals and tests for identifying acidity and alkalinity.

It was his insistence on publishing chemical theories supported by accurate experimental evidence – including details of apparatus and methods used, as well as failed experiments – which had the most impact upon modern chemistry.

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ROBERT BROWN (1773-1858)

1827 – UK

‘Tiny solid particles suspended in a fluid are in continuous random motion’

This motion is caused by constant collisions between the suspended particles and the fluid molecules.

In 1905 EINSTEIN studied Brownian motion and used it to calculate the approximate mass and size of atoms and molecules.

Robert Brown (1773-1858), British botanist. Brown is most famous for his 1827 observation of erratic motion by pollen grains in water. This was named Brownian motion.In 1877, Desaulx recognised that the motion is caused by the pollen colliding with water molecules. This meant that Brownian motion was the first directly observable evidence for the existence of molecules. Brown spent years working on plant taxonomy, establishing the classification of two major divisions of plants, the gymnosperms and the angiosperms. He also observed an essential part of living cells, which he named the nucleus (1831) &copy:

ROBERT BROWN

Brown is also remembered for discovering a small body within cells, which he named the nucleus (from the Latin for ‘little nut’). Plant cells were discovered by HOOKE.

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